South Korean University Research Aims At Boosting Lithium-Ion Battery Efficiency

South Korean University Research Aims At Boosting Li-Ion Battery Efficiency

Researchers at the Chung-Ang University in South Korea have worked on improving the efficiency of Lithium-ion batteries. Their work mainly involved in the electrolyte solutions. Lithium-ion batteries, essential for electric vehicles, face safety concerns due to polarization effects during fast charging. These researchers have now studied the impact of high-concentration electrolytes on their interface kinetics and stability, demonstrating their effectiveness in improving fast-charging abilities and preventing issues like cell swelling caused by lithium plating. These insights are expected to encourage the widespread adoption of electric vehicles and play a crucial role in reducing carbon emissions.

“Lithium-ion (Li-ion) batteries are indispensable for modern devices like electric vehicles, which play an increasingly crucial role in people’s lives. However, the main hurdle is achieving rapid charging without compromising energy density to electrify vehicles with Li-ion batteries fully. Consumers’ convenience and acceptance of electric vehicles are also influenced by factors such as their range and charging times. Additionally, using Li plating for ultra-fast charging raises safety concerns due to high cell polarization, requiring careful attention,” the university said in a media statement.

In a new study on Lithium-ion published in Energy Storage Materials, led by Associate Professor Janghyuk Moon of Chung-Ang University, researchers have introduced an innovative strategy to mitigate polarization due to concentration-based effects, addressing this challenge. Dr. Moon states, “Our study aims to enhance the range and reduce charging times of electric vehicles by developing advanced battery technologies, specifically leveraging the commonly used LiPF6 and linear carbonates in commercial batteries. By improving the kinetics and stability of batteries under fast charging conditions, we hope to make a meaningful impact on the EV industry and ultimately on people’s daily lives.”

This study investigated how using certain electrolytes, such as linear carbonate-based ones with concentrated LiPF6, affects removing the solvent (desolvation) from Li-ion and its quick insertion into the graphite anode. “To make this happen, electrolytes with low activation energy, including dimethyl carbonate, ethyl methyl carbonate, and diethyl carbonate with a special focus on dimethyl carbonate, were used to make it easier to overcome the barrier to desolvation. Laboratory tests confirmed that these electrolytes enhance the fast-charging capabilities of Li-ion batteries, as evidenced by a 1.2-Ah pouch cell retaining three times more capacity over 200 cycles. It also prevented cell swelling caused by Li plating, a common issue with traditional electrolytes,” the release said.

The study on Lithium-ion battery solution also utilized “molecular dynamics” to theoretically simulate liquid electrolyte structures at varying high and low concentrations. These aimed to understand micro-environmental changes within the battery system, offering insights into how the electrolyte affects interface kinetics and battery performance. This combined approach of practical experimentation and computational analysis highlights the significance of this study in advancing battery technology for practical applications, particularly in electric vehicles.

“By enhancing battery performance in terms of faster charging and extended range, this study directly contributes to making electric vehicles more practical and appealing to a broader electric vehicle user. If this leads to increased convenience for people, it could further boost the widespread adoption of these vehicles. In the long term, such technological improvements could play a crucial role in reducing carbon emissions and mitigating climate change, profoundly impacting people’s lives and the health of our planet,” envisions Dr. Moon, who studied the Lithium-ion battery issues.

In summary, researchers investigated the effects of cell polarization causing harmful Li plating in Li-ion batteries. They demonstrated a stepwise improvement in interfacial kinetics by the engineering of high-concentration electrolytes and additives. This study thus provides valuable insights for future electrolytes that can enhance the extremely fast-charging abilities of Li-ion batteries, potentially promoting the widespread adoption of Li-ion batteries in next-generation applications.